Yes. In both PeopleSoft HCM and Finance you can run the query called M_USER_ROLES. Look in the “Role Name” column to see the roles that each employee has. If the employee is set up in both HCM and Finance, you will need to run the query in both environments to view those roles.
NOTE: To access the M_USER_ROLES query in Finance you must have the M_KK_ENTER_BUDGETS or M_KK_INQUIRY roles; in HCM you must have the M_HR_SPECIALIST or M_HR_SPECIALIST_RDO roles